Peculiarities of Refractory Borides Formation during Mechanical Alloying IV-V Group Transition Metals with Boron in Planetary Mill
Mechanical alloying in the transition IV-V group metal-boron systems runs by the two following mechanisms: mechanically induced reaction of self-propagating synthesis determined by the enthalpy of refractory compound formation and capability to form substitutional solid solution through replacement...
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| Formato: | Capítulo de libro |
| Lenguaje: | inglés |
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IntechOpen
2020
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| Acceso en línea: | https://www.intechopen.com/chapters/70913 |
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| _version_ | 1879164700962324480 |
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| author | Savyak, Maria P. Melnick, Alex B. |
| author_browse | Melnick, Alex B. Savyak, Maria P. |
| author_facet | Savyak, Maria P. Melnick, Alex B. |
| author_sort | Savyak, Maria P. |
| building | IntechOpen |
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| description | Mechanical alloying in the transition IV-V group metal-boron systems runs by the two following mechanisms: mechanically induced reaction of self-propagating synthesis determined by the enthalpy of refractory compound formation and capability to form substitutional solid solution through replacement of a metal atom by boron atoms; and diffusion-controlled process when a supersaturated interstitial solid solution prevails and its bcc lattice gradually transforms to the hexagonal lattice of the MeB2 phase at a critical boron content. The domination of one of the above mechanisms is determined by capability of boron to form substitutional or interstitial solid solution. In the case of formation of combined (SSS and ISS) solid solutions, domination of a mechanism is determined by the interatomic bond strength as well as by the intensity of mechanical alloying. The method for calculation of the free Gibbs energy of the interstitial and substitutional solid solutions on the basis of the regular solution model was developed. It was shown that during milling tantalum and boron in a planetary mill, at first the formation of a combined solid solution occurs where two boron atoms replace one tantalum atom. Both the mechanisms of solid solution formation decrease the solution Gibbs energy. When a SSS dominates over the formation of an ISS, the Gibbs energy acquires a minimum value at a concentration of boron in tantalum of 50 at%, which leads to the solution decomposition. |
| doi_str_mv | 10.5772/intechopen.89401 |
| first_indexed | 2026-10-15T21:38:30Z |
| format | Book Chapter |
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<dc:title>Peculiarities of Refractory Borides Formation during Mechanical Alloying IV-V Group Transition Metals with Boron in Planetary Mill</dc:title>
<dc:creator>Maria P. Savyak</dc:creator>
<dc:creator>Alex B. Melnick</dc:creator>
<dc:subject>Physical Sciences, Engineering and Technology</dc:subject>
<dc:description>Mechanical alloying in the transition IV-V group metal-boron systems runs by the two following mechanisms: mechanically induced reaction of self-propagating synthesis determined by the enthalpy of refractory compound formation and capability to form substitutional solid solution through replacement of a metal atom by boron atoms; and diffusion-controlled process when a supersaturated interstitial solid solution prevails and its bcc lattice gradually transforms to the hexagonal lattice of the MeB2 phase at a critical boron content. The domination of one of the above mechanisms is determined by capability of boron to form substitutional or interstitial solid solution. In the case of formation of combined (SSS and ISS) solid solutions, domination of a mechanism is determined by the interatomic bond strength as well as by the intensity of mechanical alloying. The method for calculation of the free Gibbs energy of the interstitial and substitutional solid solutions on the basis of the regular solution model was developed. It was shown that during milling tantalum and boron in a planetary mill, at first the formation of a combined solid solution occurs where two boron atoms replace one tantalum atom. Both the mechanisms of solid solution formation decrease the solution Gibbs energy. When a SSS dominates over the formation of an ISS, the Gibbs energy acquires a minimum value at a concentration of boron in tantalum of 50 at%, which leads to the solution decomposition.</dc:description>
<dc:publisher>IntechOpen</dc:publisher>
<dc:date>2020-02-17</dc:date>
<dc:type>Chapter, Part Of Book</dc:type>
<dc:identifier>https://www.intechopen.com/chapters/70913</dc:identifier>
<dc:identifier>doi:10.5772/intechopen.89401</dc:identifier>
<dc:language>en</dc:language>
<dc:relation>ISBN:978-1-83880-040-6</dc:relation>
<dc:rights>https://creativecommons.org/licenses/by/3.0/</dc:rights>
<dc:source>https://www.intechopen.com/books/8417 ; Recent Advances in Boron-Containing Materials</dc:source>
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| id | intech-70913 |
| institution | IntechOpen |
| isbn | 978-1-83880-040-6 |
| language | English |
| last_indexed | 2026-10-15T21:38:30Z |
| publishDate | 2020 |
| publishDateRange | 2020 |
| publishDateSort | 2020 |
| publisher | IntechOpen |
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| spelling | intech-709132020-02-17 Peculiarities of Refractory Borides Formation during Mechanical Alloying IV-V Group Transition Metals with Boron in Planetary Mill Maria P. Savyak Alex B. Melnick Physical Sciences, Engineering and Technology Mechanical alloying in the transition IV-V group metal-boron systems runs by the two following mechanisms: mechanically induced reaction of self-propagating synthesis determined by the enthalpy of refractory compound formation and capability to form substitutional solid solution through replacement of a metal atom by boron atoms; and diffusion-controlled process when a supersaturated interstitial solid solution prevails and its bcc lattice gradually transforms to the hexagonal lattice of the MeB2 phase at a critical boron content. The domination of one of the above mechanisms is determined by capability of boron to form substitutional or interstitial solid solution. In the case of formation of combined (SSS and ISS) solid solutions, domination of a mechanism is determined by the interatomic bond strength as well as by the intensity of mechanical alloying. The method for calculation of the free Gibbs energy of the interstitial and substitutional solid solutions on the basis of the regular solution model was developed. It was shown that during milling tantalum and boron in a planetary mill, at first the formation of a combined solid solution occurs where two boron atoms replace one tantalum atom. Both the mechanisms of solid solution formation decrease the solution Gibbs energy. When a SSS dominates over the formation of an ISS, the Gibbs energy acquires a minimum value at a concentration of boron in tantalum of 50 at%, which leads to the solution decomposition. IntechOpen 2020-02-17 Chapter, Part Of Book https://www.intechopen.com/chapters/70913 doi:10.5772/intechopen.89401 en ISBN:978-1-83880-040-6 https://creativecommons.org/licenses/by/3.0/ https://www.intechopen.com/books/8417 ; Recent Advances in Boron-Containing Materials |
| spellingShingle | Physical Sciences, Engineering and Technology Savyak, Maria P. Melnick, Alex B. Peculiarities of Refractory Borides Formation during Mechanical Alloying IV-V Group Transition Metals with Boron in Planetary Mill |
| title | Peculiarities of Refractory Borides Formation during Mechanical Alloying IV-V Group Transition Metals with Boron in Planetary Mill |
| title_full | Peculiarities of Refractory Borides Formation during Mechanical Alloying IV-V Group Transition Metals with Boron in Planetary Mill |
| title_fullStr | Peculiarities of Refractory Borides Formation during Mechanical Alloying IV-V Group Transition Metals with Boron in Planetary Mill |
| title_full_unstemmed | Peculiarities of Refractory Borides Formation during Mechanical Alloying IV-V Group Transition Metals with Boron in Planetary Mill |
| title_short | Peculiarities of Refractory Borides Formation during Mechanical Alloying IV-V Group Transition Metals with Boron in Planetary Mill |
| title_sort | peculiarities of refractory borides formation during mechanical alloying iv v group transition metals with boron in planetary mill |
| topic | Physical Sciences, Engineering and Technology |
| url | https://www.intechopen.com/chapters/70913 |
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